She met The Hulk in a completely innocent situation. Skye had every type of hackable organisation gunning her down, even S.H.E.I.L.D was looking for her. That's why Hulk had taken her, she'd been attacked by said organisation and Hulk stepped in, saving her. Normally he would have let her be but she piped his interest, unfortunately she passed out before he could interrogate her.

When Skye did come too however she realised her predicament, out of everyone who could've saved her it was big green and angry. She sat up to see Banner looking at her in interest.
"So…" he began, Skye just looked at the man who looked very unsure of himself.
"You know I'm not scared right? Like if this is an intimidation teqnuiqe then you really need to up your game" Banner stared at her, blinking rapidly.
"You do know who I am…. Right?" he asked. Skye brushed back her hair and laughed.
"Yeah you're the incredible Hulk but I'm not scared" she announced, feeling brave. Banner smiled before getting up and leaving her.

It was a few days before Banner broached the topic of why everyone wanted her dead. She looked down as they walked across the barren field that lay behind Banners hide out.
"You'll kill me if you knew" Banner shrugged
"I won't kill you" he promised as Skye stood up a little straighter.
"I'm a hacker" she began. "I… I believe that the world deserves to know the truth, especially when people are hiding it-"
"The truth won't set you free, take me for example. People know the truth about me and they think I'm an abomination…. A freak." Sadly that didn't help Skye in the slightly. She clenched her fists.
"I'll admit the truth is a personal vendetta of mine…. I don't even know the truth about myself" Bruce frowned but Skye didn't give him the chance to speak.
"I know I shouldn't leak information but I believe the truth should be known otherwise we are just sitting ducks" she stopped when they reached a road.

"This is the end of our journey I'm afraid" Banner announced, Skye looked at him startle then to the road where her van lay.
"Skye it has been a pleasure" she nodded, grabbed her keys and walked to the van, before she got in Banner shouted her name.

"Skye just remember people can't always handle the truth"
Skye smiled but shook her head slightly and drove away.